Tsygankov, Alexey A.; Chusov, Denis published the artcile< Straightforward Access to High-Performance Organometallic Catalysts by Fluoride Activation: Proof of Principle on Asymmetric Cyanation, Asymmetric Michael Addition, CO2 Addition to Epoxide, and Reductive Alkylation of Amines by Tetrahydrofuran>, Category: chlorides-buliding-blocks, the main research area is fluoride activated organometallic catalyst preparation; asym cyanation Michael addition reductive alkylation.
The well-known transition metal catalysts can be transformed into high-performance versions by the simple use of a fluoride anion source. In situ fluoride-activated catalysts are highly active catalytic species. The isolation may lead to degradation of the species or a decrease in catalytic activity. Fluoride activation of known, relatively simple catalysts resulted in the development of one of the most efficient catalytic systems for the asym. cyanation of aldehydes, asym. Michael addition, and synthesis of cyclic carbonates. Furthermore, the fluoride-assisted reductive opening of THF with amines was developed. The proposed approach can find broad applications in the enhancement of known catalytic processes and in the design of new ones.
ACS Catalysis published new progress about Alkenes, nitro Role: SPN (Synthetic Preparation), PREP (Preparation). 5153-70-8 belongs to class chlorides-buliding-blocks, and the molecular formula is C8H6ClNO2, Category: chlorides-buliding-blocks.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics