Yan, Jingling; Wang, Zhen; Gao, Lianxun; Ding, Mengxian published the artcile< Synthesis and properties of polyimides from isomeric bis(dicarboxylphenylthio)diphenyl sulfone dianhydrides>, Recommanded Product: 5-Chloroisobenzofuran-1,3-dione, the main research area is isomeric tetracarboxylic dianhydride polyimide polysulfone preparation property; permeability permselectivity oxygen nitrogen polyimide polysulfone.
4,4′-Bis(3,4-dicarboxyphenylthio)diphenyl sulfone dianhydride(4,4′-PTPSDA) and 4,4′-bis(2,3-dicarboxyphenylthio)diphenyl sulfone dianhydride(3,3′-PTPSDA) were synthesized from chlorophthalic anhydrides and bis(4-mercaptophenyl)sulfone. Their structures were determined via IR spectra, 1H NMR and elemental anal. A series of polyimides were prepared from isomeric PTPSDAs and aromatic diamines in 1-methyl-2-pyrrolidinone (NMP) via the conventional two-step method. Polyimides based on 4,4′-PTPSDA and 3,3′-PTPSDA have good solubility in polar aprotic solvents and phenols. The 5% weight-loss temperatures of isomeric polyimides were near 500 °C in N2. DMTA and DSC analyses indicated that the glass-transition temperatures of polyimides from 3,3′-PTPSDA are higher than those of polyimides from 4,4′-PTPSDA. The wide-angle X-ray diffraction showed that all polyimides are amorphous. The polyimides from 3,3′-PTPSDA showed higher permeability but lower permselectivity compared with those from 4,4′-PTPSDA.
Polymer published new progress about Elongation at break. 118-45-6 belongs to class chlorides-buliding-blocks, and the molecular formula is C8H3ClO3, Recommanded Product: 5-Chloroisobenzofuran-1,3-dione.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics