Gung, Benjamin W.; Smith, Daniel T.; Wolf, Mark A. published the artcile< Evidence for synclinal transition state in the reactions of aromatic aldehydes with α-(alkoxy)allylstannanes>, Synthetic Route of 53581-86-5, the main research area is aldehyde aromatic reaction alkoxyallylstannane stereochem; transition state structure aldehyde reaction alkoxyallylstannane; ether enol preparation stereoselective.
Unlike aliphatic aldehydes, aromatic aldehydes produce greater than 95% of syn-(Z)-enol ether when treated with α-(alkoxy)allylstannanes in the presence of BF3·Et2O. However, in the presence of TiCl4, the reaction of p-chloro-o-methoxybenzaldehyde with α-(alkoxy)crotylstannane produced predominantly the syn-(E) isomer.
Tetrahedron published new progress about Aryl aldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 53581-86-5 belongs to class chlorides-buliding-blocks, and the molecular formula is C8H7ClO2, Synthetic Route of 53581-86-5.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics