Ishitani, Haruro; Kanai, Kan; Yoo, Woo-Jin; Yoshida, Tomoko; Kobayashi, Shu published the artcile< A Nickel-Diamine/Mesoporous Silica Composite as a Heterogeneous Chiral Catalyst for Asymmetric 1,4-Addition Reactions>, SDS of cas: 5153-70-8, the main research area is nitroalkylmalonate enantioselective preparation; supported nickel diamine complex preparation recyclable catalyst enantioselective addition; enantioselective addition malonate nitroalkene supported nickel diamine catalyst; nitromethane enantioselective addition alkylidenemalonate supported nickel diamine catalyst; asymmetric 1,4-addition; asymmetric catalysis; flow synthesis; heterogeneous catalysis; mesoporous materials.
A nonracemic nickel diamine complex supported on the mesoporous silica MCM-41 was prepared from NiI2, (R,R)-BnNHCHPhCHPhNHBn, and MCM-41 was prepared as a recyclable catalyst for the enantioselective addition of di-Me malonate to nitroalkenes and for the enantioselective addition of nitromethane to alkylidenemalonates in the presence of morpholine. MCM-41 enhanced the reactivity and improved the stability of the included nickel diamine complex.
Angewandte Chemie, International Edition published new progress about 1,3-Dicarbonyl compounds Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 5153-70-8 belongs to class chlorides-buliding-blocks, and the molecular formula is C8H6ClNO2, SDS of cas: 5153-70-8.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics