Application In Synthesis of Sodium 2,6-dichlorobenzoateOn May 31, 1986, Menkisoglou-Spyroudi, Ourania; Varvoglis, Anastasios published an article in Journal of the Chemical Society. The article was 《[Bis[(aryloxy)acetoxy]iodo]benzenes》. The article mentions the following:
The title compounds were prepared and their chem. properties studied. With iodine they gave ROCH2CO2CH2OR (I, R = aryl) via (aryloxy)acetyl hypoiodites and α-iodoanisoles. The former were unstable but were trapped with pyridine to give N-iodopyridinium (aryloxy)acetates, whereas the latter were stable and reacted independently with the title compounds to give I. The thermolysis of the title compounds was studied and, besides I, aryl (aryloxy)acetates were formed. The mechanism of the thermolysis was briefly discussed. Thus, 4-BrC6H4OCH2CO2Na in MeCN treated with (CF3CO2)2IPh gave 95% (4-BrC6H4OCH2CO2)2IPh (II). Treatment of II with iodine gave 37% 4-BrC6H4OCH2CO2CH2OC6H4Br-4 (III). Heating II at 200° for 30 min, gave 65% 4-BrC6H4OCH2CO2C6H4Br-4 and 49% III. The experimental part of the paper was very detailed, including the reaction process of Sodium 2,6-dichlorobenzoate(cas: 10007-84-8Application In Synthesis of Sodium 2,6-dichlorobenzoate)
Sodium 2,6-dichlorobenzoate(cas: 10007-84-8) belongs to organochlorine compounds. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Application In Synthesis of Sodium 2,6-dichlorobenzoate
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics