Safety of Benzylidenebis(tricyclohexylphosphine)dichlororutheniumIn 2021 ,《Polymer Skeletal Editing via Anionic Brook Rearrangements》 appeared in Journal of the American Chemical Society. The author of the article were Ratushnyy, Maxim; Zhukhovitskiy, Aleksandr V.. The article conveys some information:
This report communicates the first example of polymer backbone metamorphosis affected by anionic 1,2-Brook rearrangement of acyl silane moieties. Introduction of the acyl silane functionality into a polymer backbone was achieved via acyclic diene metathesis copolymerization (ADMET) of diene 1 and two dienes. We demonstrate that, using organolithium species and cyanide as nucleophiles, the backbones of resulting copolymers can be triggered to undergo highly efficient 1,2-Brook rearrangement, which transforms the poly(acyl silane)s into poly(silyl ether)s. Furthermore, the carbanion intermediate of the 1,2-Brook rearrangement can be intercepted by ketone electrophiles to give rise to polymers with quaternary stereogenic centers in the backbone and pendant functionality. Such structural editing of polymer backbones enables a new retrosynthetic paradigm for silicon-containing polymers that could not be accessed by traditional means. In the experimental materials used by the author, we found Benzylidenebis(tricyclohexylphosphine)dichlororuthenium(cas: 172222-30-9Safety of Benzylidenebis(tricyclohexylphosphine)dichlororuthenium)
Benzylidenebis(tricyclohexylphosphine)dichlororuthenium(cas: 172222-30-9) is the first metathesis catalyst to be widely used in organic synthesis. It is useful for acyclic diene metathesis polymerization (ADMET), Ring-Opening Metathesis Polymerization (ROMP) of strained cyclic olefins, ring opening metathesis (ROM), and so on.Safety of Benzylidenebis(tricyclohexylphosphine)dichlororuthenium
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics