Salmeia, Khalifah A.; Hodali, Hamdallah A. published the artcile< Palladium complexes with some phosphorus-sulfur ligands>, COA of Formula: C6H7ClS, the main research area is phosphinoalkylthiophene preparation complexation palladium; thiomethylphenylphosphine preparation complexation palladium; palladium phosphinoalkylthiophene thiomethylphenylphosphine complex preparation.
The P-S asym. ligands 2-(2-diphenylphosphinoethyl)thiophene (P-S2), 2-(3-diphenylphosphinopropyl)thiophene (P-S3), and [2-[(methylthio)methyl]phenyl]diphenylphosphine (P-SM) were synthesized and characterized by IR, 1H-NMR, and 13C-NMR spectroscopy. Reaction of P-S2, P-S3 or P-SM with equimolar amount of [Pd(PhCN)2Cl2] gave [Pd(P-S2)Cl2], [Pd(P-SM)Cl2] and [Pd(P-S3)(μ-Cl)Cl]2, resp. However, reaction of P-S2 with [Pd(PhCN)2Cl2] in a molar ratio of 2:1 afforded [Pd(P-S2)2Cl2]. The above complexes were characterized by microelemental anal., IR, 1H-NMR and 13C-NMR.
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry published new progress about 19995-38-1. 19995-38-1 belongs to class chlorides-buliding-blocks, and the molecular formula is C6H7ClS, COA of Formula: C6H7ClS.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics