Spitz, Cedric; Matteudi, Melanie; Tintori, Guillaume; Broggi, Julie; Terme, Thierry; Vanelle, Patrice published the artcile< Metal-Free Addition of Benzyl Halides to Aldehydes Using Super Electron Donors: Access to 3,4-Dihydroisocoumarins and 1,2-Diarylethanols>, Reference of 611-19-8, the main research area is benzyl halide aldehyde super electron donor addition; dihydroisocoumarin preparation; diarylethanol preparation.
We report here the intermol. metal-free addition reaction of functionalized benzyl halides to aldehydes using a super electron donor (SED). The metal-free and mild conditions allowed the formation of 3,4-dihydroisocoumarins and 1,2-diarylethanols with unprecedented functional group tolerance.
Journal of Organic Chemistry published new progress about Addition reaction. 611-19-8 belongs to class chlorides-buliding-blocks, and the molecular formula is C7H6Cl2, Reference of 611-19-8.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics