In 2020,Chemical Communications (Cambridge, United Kingdom) included an article by Tao, Mengna; Li, Wenbo; Zhang, Junliang. Quality Control of Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II). The article was titled 《Pd/Xiang-Phos-catalyzed enantioselective intermolecular carboheterofunctionalization of norbornene and norbornadiene》. The information in the text is summarized as follows:
A highly enantioselective Pd/Xiang-Phos-catalyzed carboheterofunctionalization of norbornene is described, giving a direct access to various chiral norbornane-fused dihydrofurans and dihydropyrroles. This synthetic methodol. provides the first example of asym. carboetherification of norbornene, and also tolerates norbornadiene well. The experimental part of the paper was very detailed, including the reaction process of Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II)(cas: 18987-59-2Quality Control of Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II))
Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II)(cas: 18987-59-2) belongs to organochlorine compounds. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. Quality Control of Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II) However, the extent of chlorination is difficult to control. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics