Whalley, David M.; Duong, Hung A.; Greaney, Michael F. published the artcile< A visible light-mediated, decarboxylative, desulfonylative Smiles rearrangement for general arylethylamines syntheses>, Quality Control of 22952-32-5, the main research area is arylethylamine preparation; alanine oxime ester decarboxylative desulfonylative Smiles rearrangement photocatalysis.
A decarboxylative, desulfonylative Smiles rearrangement is presented that employs activated-ester/energy transfer catalysis to decarboxylate β-amino acid derived starting materials at room-temperature under visible light irradiation The radical Smiles rearrangement gives a range of biol. active arylethylamine products highly relevant to the pharmaceutical industry, chem. biol. and materials science. The reaction is then applied to the synthesis of a chiral unnatural amino acid, 2-thienylalanine, used in the treatment of phenylketonuria. It was also shown how the reaction can proceed under metal-free and catalyst-free conditions.
Chemical Communications (Cambridge, United Kingdom) published new progress about Amino acids Role: RCT (Reactant), RACT (Reactant or Reagent). 22952-32-5 belongs to class chlorides-buliding-blocks, and the molecular formula is C7H6Cl2O3S, Quality Control of 22952-32-5.
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