Guerrand, Helene D. S.; Vaultier, Michel; Pinet, Sandra; Pucheault, Mathieu published the artcile< Amine-Borane Complexes: Air- and Moisture-Stable Partners for Palladium-Catalyzed Borylation of Aryl Bromides and Chlorides>, Category: chlorides-buliding-blocks, the main research area is amine borane complex air moisture stable palladium catalyzed borylation; hetero aryl bromide chloride triflate iodide palladium catalyzed borylation; aminoborane preparation; boronium ion preparation deprotonation; boronic acid derivative preparation.
A method for using amine-borane complexes directly in palladium catalyzed borylation has been developed. The reaction proceeds through the sequential formation of a boronium species followed by deprotonation leading to the aminoborane. This reagent is then directly used in the borylation process leading, after work-up, to various boronic acid derivatives The reaction was applied to (hetero)aryl triflates, iodides, bromides and chlorides.
Advanced Synthesis & Catalysis published new progress about Aryl halides Role: RCT (Reactant), RACT (Reactant or Reagent). 1435-43-4 belongs to class chlorides-buliding-blocks, and the molecular formula is C6H3ClF2, Category: chlorides-buliding-blocks.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics