Li, Yi; Shang, Jia-Qi; Wang, Xiang-Xiang; Xia, Wen-Jin; Yang, Tao; Xin, Yangchun; Li, Ya-Min published the artcile< Copper-Catalyzed Decarboxylative Oxyalkylation of Alkynyl Carboxylic Acids: Synthesis of γ-Diketones and γ-Ketonitriles>, Synthetic Route of 3240-10-6, the main research area is arylalkynylcarboxylic acid ketone nitrile decarboxylative oxyalkylation; diketone preparation; ketonitrile preparation; copper decarboxylative oxyalkylation catalyst.
A copper-catalyzed decarboxylative oxyalkylation of alkynylcarboxylic acids with ketones and alkylnitriles via direct C(sp3)-H bond functionalization to construct new C-C bonds and C-O double bonds was developed. This transformation is featured by wide functional group compatibility and the use of readily available reagents, thus affording a general approach to γ-diketones and γ-ketonitriles. A possible mechanism is proposed.
Organic Letters published new progress about Alkylation catalysts (decarboxylative oxy-). 3240-10-6 belongs to class chlorides-buliding-blocks, and the molecular formula is C9H5ClO2, Synthetic Route of 3240-10-6.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics