Sun, Bin; Shi, Xiayue; Zhuang, Xiaohui; Huang, Panyi; Shi, Rongcheng; Zhu, Rui; Jin, Can published the artcile< Photoinduced EDA Complexes Enabled Radical Tandem Cyclization/Arylation of Unactivated Alkene with 2-Amino-1,4-naphthoquinones>, Category: chlorides-buliding-blocks, the main research area is oxopyrrolidinyl arylamino naphthalenedione preparation photochem regioselective green chem; amino naphthoquinone allyl bromo difluoroacetamide cyclization arylation EDA complex.
A visible-light-induced radical tandem cyclization/arylation between 2-amino-1, 4-naphthoquinone and N-allyl-2-bromo-2,2-difluoroacetamides has been developed without an external photocatalyst. The transformation could be carried out at room temperature and gave a variety of C-3-functionalized 2-amino-1,4-naphthoquinone derivatives I (R1 = Ph, 4-MeOC6H4, 2-MeC6H4, etc.; R2 = H, 4-i-Pr, 3-Br, etc.) in moderate to excellent yields. Moreover, mechanistic studies revealed that the reaction is driven by the formation of an electron donor-acceptor (EDA) complex.
Organic Letters published new progress about Anilines Role: RCT (Reactant), RACT (Reactant or Reagent). 29027-20-1 belongs to class chlorides-buliding-blocks, and the molecular formula is C7H8ClN, Category: chlorides-buliding-blocks.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics