In 2019,Angewandte Chemie, International Edition included an article by Zhang, Wen; Wu, Lianqian; Chen, Pinhong; Liu, Guosheng. Quality Control of (3-Fluorophenyl)boronic acid. The article was titled 《Enantioselective Arylation of Benzylic C-H Bonds by Copper-Catalyzed Radical Relay》. The information in the text is summarized as follows:
A novel enantioselective copper-catalyzed arylation of benzylic C-H bonds, using alkylarenes as a limiting reagent, has been developed. A chiral bisoxazoline ligand bearing an acetate ester moiety plays a key role in both the reactivity and enantioselectivity of the reaction. The reaction provides efficient access to various chiral 1,1-diarylalkanes in good yields with good to excellent enantioselectivities, and displays excellent functional-group tolerance. The experimental part of the paper was very detailed, including the reaction process of (3-Fluorophenyl)boronic acid(cas: 768-35-4Quality Control of (3-Fluorophenyl)boronic acid)
(3-Fluorophenyl)boronic acid(cas: 768-35-4) can be used to make novel liquid crystalline fluorobiphenylcyclohexenes and difluoroterphenyls by palladium-catalyzed cross-couplings also used in the synthesis of o-phenylphenols as potent leukotriene B4 receptor agonists.Quality Control of (3-Fluorophenyl)boronic acid
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics