Zhu, Linglong; Hu, Haiwen; Qi, Liang; Zheng, Yi; Zhong, Weihui published the artcile< Enantioselective Allylic Substitution of Morita-Baylis-Hillman Adducts Catalyzed by Chiral Bifunctional Ferrocenylphosphines>, Application In Synthesis of 31166-29-7, the main research area is enantioselective allylic substitution Morita Baylis Hillman adduct ferrocenylphosphine catalyst.
A series of air-stable chiral ferrocenylphosphines (LB1-LB4) were prepared and used in the asym. allylic substitution of Morita-Baylis-Hillman (MBH) adducts with phthalimide under mild reaction conditions; the (R,SFc)-ferrocenylphosphine LB4 afforded the desired amination products in moderate yields with excellent enantioselectivities. The absolute configuration of (R)-N-[2-Methoxycarbonyl-1-(2,4-dichlorophenyl)allyl]-phthalimide was confirmed by x-ray anal.
European Journal of Organic Chemistry published new progress about Allylic substitution reaction. 31166-29-7 belongs to class chlorides-buliding-blocks, and the molecular formula is C5H2Cl2O2S, Application In Synthesis of 31166-29-7.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics