In 2019,Journal of Organic Chemistry included an article by Bosmans, Vera; Poater, Jordi; Hammink, Roel; Tinnemans, Paul; Bickelhaupt, F. Matthias; Mecinovic, Jasmin. Related Products of 768-35-4. The article was titled 《Probing Through-Space Polar-π Interactions in 2,6-Diarylphenols》. The information in the text is summarized as follows:
Although it is well established that the acidity of phenol can be fine-tuned with substituents on its aromatic ring via through-bond effects, the role of through-space effects on the acidity of phenols is presently poorly understood. Here, we present integrated exptl. and computational studies on substituted 2,6-diarylphenols that demonstrate the essential contribution from through-space OH-π interactions and O–π interactions in the observed trends in proton affinities and acidities of 2,6-diarylphenols.(3-Fluorophenyl)boronic acid(cas: 768-35-4Related Products of 768-35-4) was used in this study.
(3-Fluorophenyl)boronic acid(cas: 768-35-4) can be used to make novel liquid crystalline fluorobiphenylcyclohexenes and difluoroterphenyls by palladium-catalyzed cross-couplings also used in the synthesis of o-phenylphenols as potent leukotriene B4 receptor agonists.Related Products of 768-35-4
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics