The author of 《Photoredox-catalyzed deoxyfluorination of activated alcohols with Selectfluor》 were Gonzalez-Esguevillas, Maria; Miro, Javier; Jeffrey, Jenna L.; MacMillan, David W. C.. And the article was published in Tetrahedron in 2019. Computed Properties of C3H3ClO3 The author mentioned the following in the article:
A new visible-light photoredox catalyzed method was disclosed for the deoxyfluorination of alcs. via their corresponding oxalates, which were readily accessible in a single step and could be use without purification This radical-mediated C-F coupling was capable of fluorinating secondary and tertiary alcs. efficiently, complementing previously reported nucleophilic deoxyfluorination protocols. From a mechanistic perspective, this strategy constitute a distinct approach to the deoxyfluorination of alcs., employing an electrophilic fluorine source. In the experiment, the researchers used many compounds, for example, Methyl 2-chloro-2-oxoacetate(cas: 5781-53-3Computed Properties of C3H3ClO3)
Methyl 2-chloro-2-oxoacetate(cas: 5781-53-3) belongs to acyl chlorides. In the laboratory, acyl chlorides are generally prepared by treating carboxylic acids with thionyl chloride (SOCl2). The reaction is catalyzed by dimethylformamide and other additives.Computed Properties of C3H3ClO3
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics