Khai, Bui The; Arcelli, Antonio published an article on February 17 ,1989. The article was titled 《A new hydrogen source. 3. Chemoselective reduction with triethylammonium hypophosphite hydrate/Raney nickel and tris(triphenylphosphine)ruthenium dichloride reagents》, and you may find the article in Journal of Organic Chemistry.Reference of Ethyl 3-(4-chlorophenyl)propanoate The information in the text is summarized as follows:
Et3NH+ H2PO2-.nH2O (I) acts as a NaH2PO2·H2O modified reagent. Some advantages are noted, including higher product selectivity. Pure aromatic and aliphatic aldehydes are obtained from nitriles by the I/Raney nickel system. The homogeneous catalyst can be used with this reagent. The I/RuCl2(PPh3)3 system selectively reduces aromatic and aliphatic ketones to the corresponding alcs. with excellent yields at room temperature In the part of experimental materials, we found many familiar compounds, such as Ethyl 3-(4-chlorophenyl)propanoate(cas: 7116-36-1Reference of Ethyl 3-(4-chlorophenyl)propanoate)
Ethyl 3-(4-chlorophenyl)propanoate(cas: 7116-36-1) belongs to organochlorine compounds. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. Reference of Ethyl 3-(4-chlorophenyl)propanoate The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics