Pridmore, Simon J.; Williams, Jonathan M. J. published their research in Tetrahedron Letters on December 22 ,2008. The article was titled 《C-C bond formation from alcohols and malonate half esters using borrowing hydrogen methodology》.Product Details of 7116-36-1 The article contains the following contents:
Alcs. have been used as alkylating agents in a decarboxylative reaction with malonate half esters via a borrowing hydrogen pathway catalyzed by readily available Ru(PPh3)3Cl2. E.g., in presence of Ru(PPh3)3Cl2 and pyrrolidine, reaction of PhCH2OH and EtO2CCH2CO2H gave 88% PhCH2CH2CO2Et. The results came from multiple reactions, including the reaction of Ethyl 3-(4-chlorophenyl)propanoate(cas: 7116-36-1Product Details of 7116-36-1)
Ethyl 3-(4-chlorophenyl)propanoate(cas: 7116-36-1) belongs to organochlorine compounds. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Product Details of 7116-36-1
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics