In 2019,Organic Chemistry Frontiers included an article by Zu, Weisai; Liu, Shuai; Jia, Xin; Xu, Liang. Product Details of 768-35-4. The article was titled 《Chemoselective N-arylation of aminobenzene sulfonamides via copper catalysed Chan-Evans-Lam reactions》. The information in the text is summarized as follows:
Cu-Catalyzed Chan-Evans-Lam cross-coupling reactions between unprotected aminobenzene sulfonamides RS(O)2NH2 (R = 2-NH2C6H4, 3-NH2C6H4, 4-NH2C6H4) and arylboron nucleophiles ArB(OH)2 (Ar = 4-MeC6H4, 3,5-Me2C6H3, naphthalen-1-yl, etc.) are explored herein. Chemoselective N-arylation of aminobenzene sulfonamides could be simply enabled by the adjustment of reaction variables, such as the sources of aerobic oxidative Cu catalysis, solvents and bases. The arylation processes could be well regulated to occur on either amino or sulfonamide nitrogen atoms RS(O)2NHAr at room temperature under open flask conditions. In addition to this study using (3-Fluorophenyl)boronic acid, there are many other studies that have used (3-Fluorophenyl)boronic acid(cas: 768-35-4Product Details of 768-35-4) was used in this study.
(3-Fluorophenyl)boronic acid(cas: 768-35-4) can be used to make novel liquid crystalline fluorobiphenylcyclohexenes and difluoroterphenyls by palladium-catalyzed cross-couplings also used in the synthesis of o-phenylphenols as potent leukotriene B4 receptor agonists.Product Details of 768-35-4
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics