Chen, Wangzhe; Ni, Shengyang; Wang, Yi; Pan, Yi published an article in 2022. The article was titled 《Electrochemical-Promoted Nickel-Catalyzed Reductive Allylation of Aryl Halides》, and you may find the article in Organic Letters.Application In Synthesis of Methyl 2-chloro-2-oxoacetate The information in the text is summarized as follows:
Compared with conventional reductive coupling, reductive coupling under electrochem. conditions without external reductants is greener, milder, and more efficient and is of increasing interest to organic chemists. In this work, authors report the sacrificial anode, nickel-catalyzed electrochem. allylation reaction of aryl and alkyl halides. The reaction can be applied to a range of allylation reagents such as trifluoroalkenes, oxalates, and acetates. In the part of experimental materials, we found many familiar compounds, such as Methyl 2-chloro-2-oxoacetate(cas: 5781-53-3Application In Synthesis of Methyl 2-chloro-2-oxoacetate)
Methyl 2-chloro-2-oxoacetate(cas: 5781-53-3) belongs to acyl chlorides. In the laboratory, acyl chlorides are generally prepared by treating carboxylic acids with thionyl chloride (SOCl2). The reaction is catalyzed by dimethylformamide and other additives.Application In Synthesis of Methyl 2-chloro-2-oxoacetate
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics