In 2022,Wang, Qian; Lan, Jialing; Liang, Rong; Xia, Yihao; Qin, Lei; Chung, Lung Wa; Zheng, Zhiping published an article in ACS Catalysis. The title of the article was 《New Tricks for an Old Dog: Grubbs Catalysts Enable Efficient Hydrogen Production from Aqueous-Phase Methanol Reforming》.Application of 172222-30-9 The author mentioned the following in the article:
Herein, we report a new application of the prize-winning Grubbs catalysts, which have been widely applied for olefin metathesis, for hydrogen production from aqueous-phase methanol reforming under easily achievable conditions (1 atm, <100°C) with negligible CO formation. Out of the catalysts tested, the best turnover frequency (158 h-1) and turnover number (11424, 72 h) were both achieved with a third-generation Grubbs catalyst (G-III). The best TOF was achieved with G-III and is competitive when compared with some of the best results reported (). Also, G-III is found to be a versatile catalyst for the dehydrogenation of ethanol and formic acid. Mechanistic studies and DFT calculations shed light on the reaction mechanism, which involves an unusual substrate (solvent)-assisted six-membered-ring (σ-bond) metathesis pathway. This work should open up new opportunities in catalyst design in connection with the hydrogen economy and, more generally, with the development of clean and renewable energies. In the experiment, the researchers used Benzylidenebis(tricyclohexylphosphine)dichlororuthenium(cas: 172222-30-9Application of 172222-30-9)
Benzylidenebis(tricyclohexylphosphine)dichlororuthenium(cas: 172222-30-9) is a ruthenium-based olefin metathesis catalyst. It is useful for olefin cross metathesis (CM) and ring closing metathesis (RCM) of terminal olefins under a variety of reactions conditions, and so on.Application of 172222-30-9
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Chloride – Wikipedia,
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