《Rhodium-Catalyzed Diverse Arylation of 2,5-Dihydrofuran: Controllable Divergent Synthesis via Four Pathways》 was published in ACS Catalysis in 2020. These research results belong to Xing, Junhao; Zhu, Wanjiang; Ye, Bihai; Lu, Tao; Hayashi, Tamio; Dou, Xiaowei. Product Details of 768-35-4 The article mentions the following:
The rhodium-catalyzed controllable diverse arylation of 2,5-dihydrofuran with arylboronic acids was reported. By fine-tuning of the reaction conditions, four different ring-opening or oxidative arylation pathways were controlled in the rhodium-catalyzed arylation of 2,5-dihydrofuran, granting selective access to 2-aryl or 3-aryl homoallylic alcs. and 3-aryl or 4-aryl-2,3-dihydrofurans. The catalytic asym. ring-opening arylation of 2,5-dihydrofuran was also realized. Four plausible reaction pathways were proposed, based on the exptl. results. In the experimental materials used by the author, we found (3-Fluorophenyl)boronic acid(cas: 768-35-4Product Details of 768-35-4)
(3-Fluorophenyl)boronic acid(cas: 768-35-4) can be used to make novel liquid crystalline fluorobiphenylcyclohexenes and difluoroterphenyls by palladium-catalyzed cross-couplings also used in the synthesis of o-phenylphenols as potent leukotriene B4 receptor agonists.Product Details of 768-35-4
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics