Organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. SDS of cas: 12112-67-3.
Ilyin, I. Yu.;Mirzaeva, I. V.;Sukhikh, T. S.;Bonegardt, D. V.;Basova, T. V. research published ã?STUDY OF THE CORRELATION BETWEEN THE STRUCTURE OF THE [Ir(cod)Cp] COMPLEX AND ITS THERMAL PROPERTIESã? the research content is summarized as follows. A volatile iridium(I) complex [Ir(cod)Cp] (cod – 1,5-cyclooctadiene, Cp – cyclopentadienyl) is synthesized and characterized by IR and NMR spectroscopy. The structure of [Ir(cod)Cp] is determined by single crystal X-ray diffraction. The anal. of the Hirshfeld surface along with the electron d. distribution and its topol. based on the AIM theory reveals the presence of many intermol. contacts, with C(Cp)···H(Cp), Ir···H(Cp), H(cod)···H(cod) being the strongest. The presence of these contacts in the crystal structure of the compound leads to higher m.ps. and transition temperatures to the gas phase, as compared to those of a similar complex containing methyl-substituted cyclopentadienyl. Lattice energy calculations and results of the thermogravimetric anal. of the [Ir(cod)Cp] complex are well consistent with the similar data for β-diketonate complexes [Ir(cod)L], which suggests that there may be a correlation between lattice energies and melting and a 50% weight loss temperatures
SDS of cas: 12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
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Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics