On January 1, 2010, Gonzalez, Ana Z.; Toste, F. Dean published an article.Recommanded Product: 14602-86-9 The title of the article was Gold(I)-Catalyzed Enantioselective [4+2]-Cycloaddition of Allene-dienes. And the article contained the following:
An enantioselective gold(I)-catalyzed intramol. [4+2]-cycloaddition of allenes and dienes is reported. The reactions allow for the asym. synthesis of trans-hexahydroindenes and pyrrolidine products using C3-sym. phosphitegold(I) and ortho-arylphosphoramiditegold(I) complexes as catalysts, resp. The x-ray crystal structures of two phosphoramiditegold(I) complexes and two C3-sym. phosphitegold(I) complexes are reported. The experimental process involved the reaction of (1R,2S,5R)-2-Isopropyl-5-methylcyclohexyl carbonochloridate(cas: 14602-86-9).Recommanded Product: 14602-86-9
The Article related to phosphite gold axially chiral catalyst preparation crystal mol structure, phosphoramidite gold axially chiral catalyst preparation crystal mol structure, allene diene substrate preparation chiral gold catalyst intramol cycloaddition, hexahydroindene derivative stereoselective preparation, pyrrolidine fused derivative stereoselective preparation and other aspects.Recommanded Product: 14602-86-9
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics