Organic chlorides are organic molecules with a C-Cl bond, for example chloroform (CH3-Cl) or vinyl chloride(C2H3Cl). 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Organic chlorides can be used in production of: PVC, Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. SDS of cas: 12112-67-3.
Song, Shu-Yong;Li, Yinwu;Ke, Zhuofeng;Xu, Senmiao research published 《 Iridium-Catalyzed Enantioselective C-H Borylation of Diarylphosphinates》, the research content is summarized as follows. P-stereogenic P compounds are a ubiquitous and critically important class of chiral ligands in asym. catalysis. Methods for catalytic asym. synthesis via a step- and atom-economic way are still very limited. The authors herein disclose a protocol of phosphinate-directed Ir-catalyzed enantioselective ortho-H borylation to construct P-stereogenic P compounds A number of functional groups could be well tolerated to afford optically active diarylphosphinates with good to excellent enantioselectivities (up to 92% ee). The authors also demonstrate the synthetic utilities of the obtained borylated products, including the synthesis of precursors for chiral phosphine ligands.
12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, SDS of cas: 12112-67-3
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics