Organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Quality Control of 12112-67-3.
Tu, Hang-Fei;Nie, Yu-Han;Zheng, Chao;You, Shu-Li research published 《 Iridium-Catalyzed Intermolecular Asymmetric Allylic Amination with Pyridones》, the research content is summarized as follows. Herein a catalytic synthetic method for enantioenriched N-substituted pyridones was reported. By employing chiral iridium catalyst generated from the Carreira [P/olefin] ligand, intermol. asym. allylic amination of allyl alcs. with pyridones proceeded smoothly with excellent chemo-, regio- and enantioselectivities (>19:1 N/O, >19:1 b/l and ≥89% ee). The reaction was a kinetic resolution process under mild conditions and displayed a broad substrate scope for both pyridones and allylic alcs. The potential of this method was demonstrated by a gram-scale reaction with only 0.6 mol% catalyst loading and diverse transformations of the amination products to useful skeletons.
Quality Control of 12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
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Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics