The class of organic compounds having covalently a bonded chlorine atom is called organic chlorides. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Their wide structural variety and divergent chemical properties lead to a broad range of named reactions and applications. Application of C16H24Cl2Ir2.
Zhou, Lei;Zhang, Dejin;Hu, Jinling;Wu, Youting;Geng, Jiao;Hu, Xingbang research published 《 Thermal Dehydrogenation and Hydrolysis of BH3NH3 Catalyzed by Cyclic (Alkyl)(amino)carbene Iridium Complexes under Mild Conditions》, the research content is summarized as follows. Though NH3-borane (AB) is recognized as an excellent H storage material, efficient dehydrogenation of AB still remains a challenge. Herein, the authors report that cyclic (alkyl)(amino)carbene Ir complexes are highly efficient for both the thermal dehydrogenation and hydrolysis of AB under mild conditions. At 30°, the two processes are completed within 15 and 5 min, releasing 2.1 and 2.8 equiv of H2 per AB, resp. Also, 2.8 equiv of H2 can be released within 10 min by thermal dehydrogenation at 60°. Kinetic studies revealed that the activation energies for thermal dehydrogenation and hydrolysis of AB are 10.7 and 8.5 kcal/mol, resp. The catalyst can be recycled without significant loss of activity at least six times for both processes. The reaction mechanisms were further explored by theor. calculations, stoichiometric reactions, and kinetic isotope effect experiments
Application of C16H24Cl2Ir2, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
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Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics