On December 20, 2013, Chae, Sang Youl; Yoon, Young Wook; Lee, Sang Kuk published an article.Synthetic Route of 452-75-5 The title of the article was Vibronic spectroscopy of jet-cooled benzyl-type radicals produced from 2-fluoro-4-chlorotoluene by corona discharge. And the article contained the following:
A home-made pinhole-type glass nozzle was employed to generate vibronically excited but jet-cooled benzyl-type radicals from precursor 2-fluoro-4-chlorotoluene with a large amount of carrier gas He, from which the visible vibronic emission spectrum was recorded with a long-path monochromator. From an anal. of the spectrum observed, it was found that two benzyl-type radicals, 2-fluorobenzyl and 2-fluoro-4-chlorobenzyl radicals, were formed from the precursor in corona discharge. The possible pathway for the production of benzyl-type radicals that can explain the spectroscopic observation is herein proposed. In addition, the electronic energy of the D1 → D0 transition and the vibrational mode frequencies in the D0 state of the 2-fluoro-4-chlorobenzyl radical were determined for the first time. The experimental process involved the reaction of 4-Chloro-2-fluorotoluene(cas: 452-75-5).Synthetic Route of 452-75-5
The Article related to benzyl type radical corona discharge reaction mechanism, Physical Organic Chemistry: Absorption, Emission, Reflection, and Scattering Spectra (Ultraviolet and Visible, Infrared and Fourier Transform Infrared, Raman, Microwave, Photoelectron, Fluorescence, Phosphorescence, etc.) and other aspects.Synthetic Route of 452-75-5
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics