Jurga, Stefan published an article in 1980, the title of the article was Nuclear magnetic relaxation studies in solids.Recommanded Product: trimethyloxosulphonium chloride And the article contains the following content:
Spin-lattice relaxation times in the laboratory and in the rotating frame are reported for trimethyloxosulfonium fluoride, chloride, bromide and iodide as well as for Me2SO and Me2SO2 over a wide temperature range. A model was developed that makes it possible to analyze the exptl. data on the basis of 4 independent reorientations around 3 3-fold axis and around center of gravity . The following conclusions consistent with the 2nd moment and spin-lattice relaxation results are drawn about reorientational state of cations and mols. The Me group is reorienting about its 3-fold axis at random between 3 equilibrium positions separated by 120° in all the compounds A 3-fold reorientation of all cations around the C3 axis (designed by S → O bond) occurs. There is dynamical inequivalence of Me groups within the Me2SO mol. and trimethyloxosulfonium chloride with 1:2 ratio. There is observed translational diffusion in Me2SO2. The activation energies for C3 and C’3 reorientations decrease with an increase of an anion ionic radius (with exception of the iodide salt for the last motion). The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).Recommanded Product: trimethyloxosulphonium chloride
The Article related to spin lattice relaxation solid, dimethyl sulfone spin lattice relaxation, sulfoxide dimethyl spin lattice relaxation, trimethyloxosulfonium halide spin lattice, sulfonium salt spin lattice relaxation and other aspects.Recommanded Product: trimethyloxosulphonium chloride
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics