On May 4, 2020, Maeda, Chihiro; Nagahata, Keiji; Shirakawa, Takuma; Ema, Tadashi published an article.Related Products of 14602-86-9 The title of the article was Azahelicene-Fused BODIPY Analogues Showing Circularly Polarized Luminescence. And the article contained the following:
Helical carbazole-based BODIPY analogs I (X = O, S; Y = F or YY = 1,1′-binaphthalene-2,2′-diolato; R = H, RR = benzo) were readily synthesized via aza[7]helicenes. The structures of azahelicene-incorporated BF2 dyes were elucidated by x-ray diffraction anal. DFT calculations revealed that the π-conjugated system expanded from the helicene moiety to the BODIPY framework. The azahelicene-fused boron complexes showed the Cotton effects and the circularly polarized luminescence (CPL) in the visible region. Furthermore, an axially chiral binaphthyl group was attached to the helically chiral dyes, which enhanced the chiroptical properties. The experimental process involved the reaction of (1R,2S,5R)-2-Isopropyl-5-methylcyclohexyl carbonochloridate(cas: 14602-86-9).Related Products of 14602-86-9
The Article related to bodipy azahelicene boron preparation benzothiazole benzoxazole derivative resolution, cd fluorescence cotton effect azahelicene benzothiazole benzoxazole bodipy, crystal structure bodipy azahelicene boron benzothiazole benzoxazole complex and other aspects.Related Products of 14602-86-9
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics