On July 16, 2021, Cai, Wei; Zhou, Yiming; He, Yanlin; Chen, Kaihong; Yu, Cui; Huang, You published an article.COA of Formula: C11H19ClO2 The title of the article was Designing and Accurately Developing a [6 + 2] Dipolar Cycloaddition for the Synthesis of Benzodiazocines. And the article contained the following:
Herein, a concept for the design of 1,6-dipoles that bypasses the regioselectivity was described. Through the introduction of an amino group into Morita-Baylis-Hillman (MBH) carbonates, unprecedented [6 + 2] dipolar cycloadditions were accurately developed with Cs2CO3, efficiently delivering a series of benzodiazocines I (R1 = 9-Cl, 10-Me, 8-OMe, etc., R2 = Me, Et, i-Bu, etc.; R3 = OMe, OAllyl, Ph, etc.; R4 = 4-MeC6H4, 2,4-F2C6H3, 1-naphthyl, etc.) in mild conditions. Computational studies bring a deeper understanding of this reaction. The experimental process involved the reaction of (1R,2S,5R)-2-Isopropyl-5-methylcyclohexyl carbonochloridate(cas: 14602-86-9).COA of Formula: C11H19ClO2
The Article related to benzodiazocine preparation, morita baylis hillman carbonate isocyanate dipolar cycloaddition, Heterocyclic Compounds (More Than One Hetero Atom): Eight- and Higher-Membered Rings and other aspects.COA of Formula: C11H19ClO2
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics