On June 3, 2015, Duffy, Brian C.; Howard, Kyle T.; Chisholm, John D. published an article.Name: tert-Butyl trichloroacetimidate The title of the article was Alkylation of thiols with trichloroacetimidates under neutral conditions. And the article contained the following:
Trichloroacetimidates are displaced with thiols to form the corresponding sulfides without the need for an added acid or base by simply heating the reactants in refluxing THF. This operationally simple procedure provides the corresponding sulfides in excellent yields with only the formation of the neutral trichloroacetamide as the side product. The imidate may also be formed in situ, allowing for a direct method for the formation of sulfides from alcs. This reaction provides a general method for the synthesis of a variety of sulfides from inexpensive and readily available alc. starting materials. The experimental process involved the reaction of tert-Butyl trichloroacetimidate(cas: 98946-18-0).Name: tert-Butyl trichloroacetimidate
The Article related to thiol trichloroacetimidate substitution alkylation, sulfide preparation, General Organic Chemistry: Synthetic Methods and other aspects.Name: tert-Butyl trichloroacetimidate
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics