On June 21, 2019, Mahajani, Nivedita S.; Meador, Rowan I. L.; Smith, Tomas J.; Canarelli, Sarah E.; Adhikari, Arijit A.; Shah, Jigisha P.; Russo, Christopher M.; Wallach, Daniel R.; Howard, Kyle T.; Millimaci, Alexandra M.; Chisholm, John D. published an article.Safety of tert-Butyl trichloroacetimidate The title of the article was Ester Formation via Symbiotic Activation Utilizing Trichloroacetimidate Electrophiles. And the article contained the following:
Trichloroacetimidates are useful reagents for the synthesis of esters under mild conditions that do not require an exogenous promoter. These conditions avoid the undesired decomposition of substrates with sensitive functional groups that are often observed with the use of strong Lewis or Bronsted acids. With heating, these reactions have been extended to benzyl esters without electron-donating groups. These inexpensive and convenient methods should find application in the formation of esters in complex substrates. The experimental process involved the reaction of tert-Butyl trichloroacetimidate(cas: 98946-18-0).Safety of tert-Butyl trichloroacetimidate
The Article related to ester formation symbiotic activation chloroacetimidate electrophile, General Organic Chemistry: Synthetic Methods and other aspects.Safety of tert-Butyl trichloroacetimidate
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics