On July 9, 2015, Agapiou, A.; Zorba, E.; Mikedi, K.; McGregor, L.; Spiliopoulou, C.; Statheropoulos, M. published an article.Application In Synthesis of (1R,2S,5R)-2-Isopropyl-5-methylcyclohexyl carbonochloridate The title of the article was Analysis of volatile organic compounds released from the decay of surrogate human models simulating victims of collapsed buildings by thermal desorption-comprehensive two-dimensional gas chromatography-time of flight mass spectrometry. And the article contained the following:
Field experiments were devised to mimic the entrapment conditions under the rubble of collapsed buildings aiming to investigate the evolution of volatile organic compounds (VOCs) during the early dead body decomposition stage. Three pig carcasses were placed inside concrete tunnels of a search and rescue (SAR) operational field terrain for simulating the entrapment environment after a building collapse. The exptl. campaign employed both laboratory and on-site anal. running in parallel. The current work focuses only on the results of the laboratory using thermal desorption coupled to comprehensive two-dimensional gas chromatog. with time-of-flight mass spectrometry (TD-GC × GC-TOF MS). The flow-modulated TD-GC × GC-TOF MS provided enhanced separation of the VOC profile and served as a reference for the evaluation of the on-site anal. in the current exptl. campaign. Bespoke software was used to deconvolve the VOC profile to extract as much information as possible into peak lists. In total, 288 unique VOCs were identified (i.e., not found in blank samples). The majority were aliphatics (172), aromatics (25) and nitrogen compounds (19), followed by ketones (17), esters (13), alcs. (12), aldehydes (11), sulfur, miscellaneous and acid compounds The TD-GC × GC-TOF MS proved to be a sensitive and powerful system for resolving the chem. puzzle of above-ground “scent of death”. The experimental process involved the reaction of (1R,2S,5R)-2-Isopropyl-5-methylcyclohexyl carbonochloridate(cas: 14602-86-9).Application In Synthesis of (1R,2S,5R)-2-Isopropyl-5-methylcyclohexyl carbonochloridate
The Article related to volatile organic compound analysis human decay model gc ms, decomposition, forensic chemistry, pig carcass, two-dimensional gas chromatography, volatiles, Toxicology: Methods (Including Analysis) and other aspects.Application In Synthesis of (1R,2S,5R)-2-Isopropyl-5-methylcyclohexyl carbonochloridate
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics