Simonetta, Massimo; Carra’, Sergio published an article in 1957, the title of the article was Reaction velocity of some ο- and p-chloronitrotoluenes with sodium methylate.Application of 38939-88-7 And the article contains the following content:
The reaction velocity at 70, 80, and 90° of 6 isomeric chloronitrotoluenes and 6 isomeric chloronitroanisoles was measured in MeOH with MeONa [position of Cl, NO2, and Me (and MeO) and 105K (l. mole-1. sec.-1) given]: 1, 4, 2, 4.86, 3.82; 1, 4, 3, 5.08, 10.69; 1, 2, 6, 0.77, 1.19; 1, 2, 5, 4.19, 14.56; 1, 2, 4, 1.37, 0.69; 1, 2, 3, 0.68, 0.61. The results were compared with those of Miller and Williams (C.A. 48, 5815h) for the reaction of the same compounds with piperidine in C6H6 and with those of Brieux and Deulofen (C.A. 49, 8158a). 19 references. The experimental process involved the reaction of 2-Chloro-4-methyl-1-nitrobenzene(cas: 38939-88-7).Application of 38939-88-7
2-Chloro-4-methyl-1-nitrobenzene(cas:38939-88-7) belongs to chlorides. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst. Application of 38939-88-7
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics