Fadeeva, Anastasia A. published the artcileChlorination of Conjugated Nitroalkenes with PhICl2 and SO2 Cl2 for the Synthesis of α-Chloronitroalkenes, Computed Properties of 61343-99-5, the main research area is conjugated nitroalkene iodobenzene dichloride chemoselective chlorination; sulfuryl chloride conjugated nitroalkene chemoselective chlorination; chloro nitroalkene preparation.
Chlorination of conjugated nitroalkenes with iodobenzene dichloride or sulfuryl chloride to give target α-chloronitroalkenes in good yields was described. Details of the procedure depend on the donating ability of the nitroalkene substituents. The activity of the described chlorinating agents increases in order ‘PhICl2/Py’ < 'SO2Cl2' < 'SO2Cl2/HCl' with the former produced the best yields for highly donating substrates and the latter for non-activated groups. An autocatalytic role of hydrogen chloride and the chemoselectivity of chlorination were also demonstrated. Synthesis published new progress about Aryl aldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 61343-99-5 belongs to class chlorides-buliding-blocks, name is 4-(4-Chlorophenoxy)benzaldehyde, and the molecular formula is C13H9ClO2, Computed Properties of 61343-99-5.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics