Karad, Somnath Narayan published the artcileEnantioselective Synthesis of Chiral Cyclopent-2-enones by Nickel-Catalyzed Desymmetrization of Malonate Esters, Recommanded Product: 3-Chloro-4-isopropoxyphenylboronic acid, the main research area is chiral cyclopentenone enantioselective synthesis; crystal mol structure phenyl cyclopentenone; nickel catalyzed desymmetrization alkynyl malonate ester arylboronic acid; asymmetric catalysis; carbocycles; cyclization; isomerization; nickel.
The enantioselective synthesis of highly functionalized chiral cyclopent-2-enones by the reaction of alkynyl malonate esters with arylboronic acids is described. These desymmetrizing arylative cyclizations are catalyzed by a chiral phosphinooxazoline/nickel complex, and cyclization is enabled by the reversible E/Z isomerization of alkenylnickel species. The general methodol. is also applicable to the synthesis of 1,6-dihydropyridin-3(2H)-ones.
Angewandte Chemie, International Edition published new progress about Arylboronic acids Role: RCT (Reactant), RACT (Reactant or Reagent). 480438-56-0 belongs to class chlorides-buliding-blocks, name is 3-Chloro-4-isopropoxyphenylboronic acid, and the molecular formula is C9H12BClO3, Recommanded Product: 3-Chloro-4-isopropoxyphenylboronic acid.
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Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics