Tsvelikhovsky, Dmitry published the artcileConcise Palladium-Catalyzed Synthesis of Dibenzodiazepines and Structural Analogues, COA of Formula: C7H3BrClF3O, the main research area is dibenzodiazepine dibenzooxazepine preparation palladium copper catalyzed cross coupling; aniline dihaloarene reactant palladium catalyzed coupling diarylamine preparation; diarylamine reactant palladium catalyzed cross coupling dibenzodiazepine preparation; phenol dihaloarene reactant palladium catalyzed coupling diarylether preparation; diarylether reactant palladium catalyzed cross coupling dibenzodiazepine preparation.
A general and highly efficient protocol for the synthesis of dibenzodiazepines and their structural analogs is reported. In the presence of catalytic quantities of palladium, readily accessible precursors are cross-coupled with ammonia and then spontaneously undergo an intramol. condensation to form the corresponding dibenzodiazepines, e.g. I, in one step. This new strategy is applicable to the construction of a wide variety of dibenzooxazepines, e.g. II, and other structurally related heterocycles, e.g. III.
Journal of the American Chemical Society published new progress about Aromatic amines Role: RCT (Reactant), RACT (Reactant or Reagent). 468075-00-5 belongs to class chlorides-buliding-blocks, name is 2-Bromo-1-chloro-4-(trifluoromethoxy)benzene, and the molecular formula is C7H3BrClF3O, COA of Formula: C7H3BrClF3O.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics