Yap, Connor published the artcileEnantioselective Nickel-Catalyzed Intramolecular Allylic Alkenylations Enabled by Reversible Alkenylnickel E/Z Isomerization, Product Details of C9H12BClO3, the main research area is alkynylallylic phosphate arylboronic acid nickel enantioselective allylic alkenylation isomerization; allylic substitution; asymmetric catalysis; cyclization; isomerization; nickel.
Enantioselective nickel-catalyzed arylative cyclizations of substrates containing a Z-allylic phosphate tethered to an alkyne are described. These reactions give multisubstituted chiral aza- and carbocycles, and are initiated by the addition of an arylboronic acid to the alkyne, followed by cyclization of the resulting alkenylnickel species onto the allylic phosphate. The reversible E/Z isomerization of the alkenylnickel species is essential for the success of the reactions.
Angewandte Chemie, International Edition published new progress about Alkenylation catalysts (stereoselective, intramol., allylic). 480438-56-0 belongs to class chlorides-buliding-blocks, name is 3-Chloro-4-isopropoxyphenylboronic acid, and the molecular formula is C9H12BClO3, Product Details of C9H12BClO3.
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Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics