Dai, Rongrong et al. published their research in Molecular Catalysis in 2022 | CAS: 13820-53-6

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Computed Properties of Cl4Na2Pd

Pd/Ni-Al hydrotalcite for base-free alcohol oxidation: Dependency of activity and selectivity on palladium precursors and reduction reagents was written by Dai, Rongrong;Guo, Zheng. And the article was included in Molecular Catalysis in 2022.Computed Properties of Cl4Na2Pd The following contents are mentioned in the article:

Benzyl alc. was chosen as a model substrate for Pd/hydrotalcite mediated selective oxidation of alcs. to investigate the roles of palladium precursors (Na2PdCl4, K2PdCl4, PdCl2), reduction reagents (N2H4 and NaBH4), and Pd loading amount in determining structure-activity relationship of flower-like nano-catalyst. XRD analyses show typical characteristic peaks of all hydrotalcites regardless of palladium precursors; whereas TEM studies show a larger mean size of Pd nanoparticles obtained with reducing reagent N2H4 over NaBH4. However, the difference in particle sizes didn’t result in a significant difference in benzyl alc. conversion, but extended to catalytic selectivity where N2H4-reduced Pd/hydrotalcite achieved 94%-96% selectivity over 88%-93% by NaBH4. FTIR-CD3CN surface acidity study suggested that a stronger acidity of N2H4 reduced Pd/hydrotalcite may account for its better selectivity. 3% Pd/hydrotalcite with N2H4 as reducing reagent demonstrated the best catalytic performance; and was successfully extended to oxidation of 17 aromatic and aliphatic alcs. The conversion of alcs. is strongly dependent on individual alc. mol. structure and electronic effect; but all reactions showed medium-to-excellent selectivity. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Computed Properties of Cl4Na2Pd).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Computed Properties of Cl4Na2Pd

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics