Facts or Artifacts: Pitfalls in Quantifying Sub-ppm Levels of Ammonia Produced from Electrochemical Nitrogen Reduction was written by Biswas, Suchi Smita;Saha, Arunava;Eswaramoorthy, Muthusamy. And the article was included in ACS Omega in 2022.Application of 13820-53-6 The following contents are mentioned in the article:
Synthesis of NH3 through electrochem. N reduction (ENR) is emerging as one of the attractive research areas in recent years, notwithstanding the enormous challenges it faces in quantification of NH3 at very low concentrations Several reports claiming high production rate are unwittingly compromised by the accuracy of analyzing a very low concentration (<1 ppm) of NH3 in the electrolyte post-ENR reaction using the indophenol method. Therefore, the authors have highlighted the significance of selecting and standardizing a right protocol encompassing admissible levels of oxidants and a complexing agent, citrate (to mitigate the effect of interfering metal ions), through elaborate control experiments The importance of setting the lowest limit of NH3 concentration that can be accurately quantified by the indophenol method is also justified. Further, the exptl. observations were summarized into a protocol, which was followed to reevaluate the performance of two well-claimed electrocatalysts for ENR reported recently in the literature. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Application of 13820-53-6).
Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Application of 13820-53-6
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics