Tri-metallic AuPdIr nanoalloy towards efficient hydrogen generation from formic acid was written by Liu, Dong-Xue;Zhou, Yi-Tong;Zhu, Yong-Fu;Chen, Ze-Yu;Yan, Jun-Min;Jiang, Qing. And the article was included in Applied Catalysis, B: Environmental in 2022.Recommanded Product: Sodium tetrachloropalladate(II) The following contents are mentioned in the article:
Formic acid (FA), as a safe and renewable hydrogen storage material, attracts extensive attention. Herein, an efficient catalyst Au0.35Pd0.5Ir0.15 nanoalloy supported on NH2-N-rGO has been successfully synthesized and applied for hydrogen generation from FA. It is found by d. function theory (DFT) calculation that addition of Ir into AuPd alloy can change the initial adsorption configuration of HCOOH* and thus reduce the energy barrier of rate determining step (RDS) of FA dehydrogenation. As a result, Au0.35Pd0.5Ir0.15/NH2-N-rGO displays 100% conversion, 100% selectivity even after 150 days for FA dehydrogenation at 298 K, and the initial turnover frequency (TOF) can reach the recorded value (12781.2 h-1) without any additives. More interestingly, it is proved to be a universal method to design the effective catalysts for hydrogen generation from FA by the high activities of other tri-metallic alloys with addition of other high γ elements (such as Pt, Rh, and Ru). This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Recommanded Product: Sodium tetrachloropalladate(II)).
Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Recommanded Product: Sodium tetrachloropalladate(II)
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics