Small Variations, Big Impact: Structural Diversity of the Complexes of a Phosphane-Decorated Benzenedithiol with Group-11 Metals was written by Schlindwein, Simon H.;Nieger, Martin;Gudat, Dietrich. And the article was included in European Journal of Inorganic Chemistry in 2021.Category: chlorides-buliding-blocks The following contents are mentioned in the article:
Reaction of a phosphine-decorated benzenedithiol (pbdtH2) with coinage metal salts furnished polynuclear complexes [M2(pbdtH)2] (M = AuI) or [cat][M5(pbdt)3] (cat = unipos. cation, M = AgI, CuI), which were characterized by anal. and spectroscopic techniques and single-crystal x-ray diffraction studies. Also, a double salt with an anion [Ag5(pbdt)3(PPh3)]– that proved unstable in solution was characterized crystallog. The spectroscopic and crystallog. data revealed that the Cu(I) and Ag(I) complexes exhibit, despite their like stoichiometric composition, isomeric mol. structures. The observed disparities were reproduced by DFT studies. The dinuclear Au(I) complex was found to undergo air-oxidation to furnish a mixed-valent complex [(AuIII)2(AuI)2(pbdt)4]. The copper(I) – but not the isomeric silver(I) complexes – showed luminescence in the solid state. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Category: chlorides-buliding-blocks).
Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Category: chlorides-buliding-blocks
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics