The effect of the sp3/sp2 carbon ratio on the electrochemical oxidation of 2,4-D with p-Si BDD anodes was written by Souza, F. L.;Saez, C.;Lanza, M. R. V.;Canizares, P.;Rodrigo, M. A.. And the article was included in Electrochimica Acta in 2016.Synthetic Route of C6H5ClO2 The following contents are mentioned in the article:
B-doped diamond films on Si substrates (p-Si BDD) with different sp3/sp2 C ratios are systematically varied in electrodes used to oxidize 2,4-dichlorophenoxyacetic acid (2,4-D) in synthetic wastewater containing chlorides. 2,4-D is completely mineralized during the electrolysis. A higher sp3/sp2 ratio in the anode results in a more rapid and efficient oxidative removal of 2,4-D. Chlorinated compounds such as 4-chlororesorcinol, 2-chlorophenol, and 2,4-dichlorophenol form as intermediates during the oxidative treatment. Although these compounds are completely depleted during the electrolysis, their maximum observed concentrations decrease as the sp3 content increases in the anode. On the contrary, higher maximum concentrations are observed for nonchlorinated intermediates, especially hydroquinone, and there is a greater formation of chlorates and perchlorates in chloride-containing solutions as the sp3 content increases in the anode. This study involved multiple reactions and reactants, such as 4-Chlororesorcinol (cas: 95-88-5Synthetic Route of C6H5ClO2).
4-Chlororesorcinol (cas: 95-88-5) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Synthetic Route of C6H5ClO2
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics