Engineering the atomic interface of porous ceria nanorod with single palladium atoms for hydrodehalogenation reaction was written by Li, Zhijun;Zhang, Mingyang;Zhang, Lili;Dong, Xiuli;Leng, Leipeng;Horton, J. Hugh;Wang, Jun. And the article was included in Nano Research in 2022.Name: Sodium tetrachloropalladate(II) The following contents are mentioned in the article:
Tuning the electronic properties of single atom catalysts (SACs) between the central metal and the neighboring surface atoms has emerged as an efficient strategy to boost catalytic efficiency and metal utilization. Here we describe a simple and efficient approach to create atomically dispersed palladium atoms supported over defect-contg porous ceria nanorod contg palladium up to 0.26 weight The existence of singly dispersed palladium atoms is confirmed by spherical aberration correction electron microscopy and extended X-ray absorption fine structure measurements. This catalyst shows excellent efficiency in hydrodehalogenation reactions at low H2 pressure under mild conditions, along with satisfactory recyclability and scalability. D. functional theory (DFT) calculations reveal that the high activity stems from the spatial isolation of palladium atoms and the modified electronic structure of palladium confined in defect-containing ceria nanorod. This work may lay the foundation for the facile creation of single atom catalysts within the synthetic community and shed light on the possibility for scale-up prodn graphic not available see fulltext. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Name: Sodium tetrachloropalladate(II)).
Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Name: Sodium tetrachloropalladate(II)
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Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics