Preparation of the CNTs/AG/ITO electrode with high electro-catalytic activity for 2-chlorophenol degradation and the potential risks from intermediates was written by Liu, Haiyang;Zhang, Zhaocheng;Ren, Miao;Guan, Jiunian;Lu, Nan;Qu, Jiao;Yuan, Xing;Zhang, Ya-nan. And the article was included in Journal of Hazardous Materials in 2018.HPLC of Formula: 95-88-5 The following contents are mentioned in the article:
A novel carbon nanotubes (CNTs)/agarose (AG)/ITO electrode with high electro-catalytic activity was prepared using a simple sol-gel method. Characterization results showed that the prepared CNTs/AG membrane, coated on the ITO conductive glass, was consisted of C and O. The electro-catalytic degradation for 2-chlorophenol (2-CP) and the influence factors were investigated. The results meant that electro-catalytic degradation for 2-CP was highly dependent on pH, bias voltage, and catalyst dosage. At pH 2, 4V bias voltage, and 5wt% CNTs dosage, the electro-catalytic efficiency of CNTs/AG/ITO electrode for 2-CP (20 mg/L) achieved 98% within 180 min. Afterwards, the electro-catalytic properties of recycling electrode, roles of the generated reactive oxygen species, and the reaction pathways were also investigated and proposed. In addition, the toxicities of the generated intermediates from the electro-catalytic degradation were calculated by easy methods. The results indicated that the toxicities of some intermediates were higher than the parent pollutant, especially the formation of 2-CP dimer which was seldom reported in the advanced oxidation process. The findings of using AG as the carrier and conductive adhesive for catalytic material and the assessment methods for the possible increasing risks from the intermediates were reported firstly in this paper. This study involved multiple reactions and reactants, such as 4-Chlororesorcinol (cas: 95-88-5HPLC of Formula: 95-88-5).
4-Chlororesorcinol (cas: 95-88-5) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.HPLC of Formula: 95-88-5
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics