Direct Reduction of 1-Bromo-6-chlorohexane and 1-Chloro-6-iodohexane at Silver Cathodes in Dimethylformamide was written by Rose, John A.;McGuire, Caitlyn M.;Hansen, Angela M.;Karty, Jonathan A.;Mubarak, Mohammad S.;Peters, Dennis G.. And the article was included in Electrochimica Acta in 2016.Formula: C6H12BrCl The following contents are mentioned in the article:
Cyclic voltammetry and controlled-potential (bulk) electrolyzes were employed to probe the electrochem. reductions of 1-bromo-6-chlorohexane and 1-chloro-6-iodohexane at Ag cathodes in DMF containing 0.050M Bu4N tetrafluoroborate (TBABF4). A cyclic voltammogram for reduction of 1-bromo-6-chlorohexane shows a single major irreversible cathodic peak, whereas reduction of 1-chloro-6-iodohexane gives rise to a pair of irreversible cathodic peaks. Controlled-potential (bulk) electrolyzes of 1-bromo-6-chlorohexane at a Ag gauze cathode reveal that the process involves a two-electron cleavage of the C-Br bond to afford 1-chlorohexane as the major product, along with 6-chloro-1-hexene, n-hexane, 1-hexene, and 1,5-hexadiene as minor species. In contrast, bulk electrolyzes of 1-chloro-6-iodohexane indicate that the 1st voltammetric peak corresponds to a 1-electron process, giving a dimer (1,12-dichlorododecane) together with 1-chlorohexane and 6-chloro-1-hexene as well as 1-hexene and 1,5-hexadiene in trace amounts At potentials corresponding to the 2nd cathodic peak, reduction of 1-chloro-6-iodohexane is a mixture of 1- and two-electron steps that yields the same set of products, but in different proportions. Mechanistic schemes probably explain the electrochem. behavior of both 1-bromo-6-chlorohexane and 1-chloro-6-iodohexane. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Formula: C6H12BrCl).
1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Formula: C6H12BrCl
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics