Base-free Oxidative Esterification of HMF over AuPd/nNiO-TiO2. When Alloying Effects and Metal-support Interactions Converge in Producing Effective and Stable Catalysts was written by Campisi, Sebastiano;Bellomi, Silvio;Chinchilla, Lidia E.;Prati, Laura;Villa, Alberto. And the article was included in ChemCatChem in 2022.Category: chlorides-buliding-blocks The following contents are mentioned in the article:
Furan-2,5-dimethylcarboxylate (FDMC), along with ethylene glycol (EG), is the key monomer to produce (poly-(ethylene-furanoate) (PEF). Noble metal-based catalysts can convert hydroxymethyl furfural (HMF) to FDMC in methanol through liquid phase catalytic oxidative esterification. In this work, the catalytic performance of Au, Pd and AuPd NPs supported on nanosized nickel oxide (nNiO) have been evaluated under base-free conditions at 90 °C and 3 bar O2. Synergistic effects between Au and Pd imparted high activity and higher yield to FDMC compared to the monometallic counterparts. The role of support was also investigated by depositing AuPd NPs on TiO2 and nNiO-TiO2. Remarkable yield to FDMC (85 % after 8 h) and high stability were observed over AuPd/ nNiO-TiO2 catalyst. This peculiar catalytic behavior could be imputed to the formation of trimetallic AuPdNi particles offering highly active interfacial sites. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Category: chlorides-buliding-blocks).
Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Category: chlorides-buliding-blocks
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics