Cooperative veratryle and nitroindoline cages for two-photon uncaging in the NIR was written by Cueto Diaz, Eduardo;Picard, Sebastien;Klausen, Maxime;Hugues, Vincent;Pagano, Paolo;Genin, Emilie;Blanchard-Desce, Mireille. And the article was included in Chemistry – A European Journal in 2016.Recommanded Product: 1-Bromo-6-chlorohexane The following contents are mentioned in the article:
Tandem uncaging systems in which a two-photon absorbing module and a cage moiety, linked via a phosphorous clip, that act together by Foerster resonance energy transfer (FRET) have been developed. A library of these compounds, using different linkers and cages (7-nitroindolinyl or nitroveratryl) has been synthesized. The investigation of their uncaging and two-photon absorption properties demonstrates the scope and versatility of the engineering strategy towards efficient two-photon cages and reveals surprising cooperative and topol. effects. The interactions between the 2PA module and the caging moiety are found to promote cooperative effects on the 2PA response while addnl. processes that enhance the uncaging efficiency are operative in well-oriented nitroindoline-derived dyads. These synergic effects combine to lead to record two-photon uncaging cross-section values (i.e., up to 20 GM) for uncaging of carboxylic acids. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Recommanded Product: 1-Bromo-6-chlorohexane).
1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Recommanded Product: 1-Bromo-6-chlorohexane
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Chlorides – an overview | ScienceDirect Topics